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JACS Au, 23 September 2024, Volume 4, Issue 9

JACS Au, 23 September 2024, Volume 4, Issue 9

Posted on 2024/09/23

by sg_portfolio

Angular triquinane moiety
Carbocation cascade
Carbocation-mediated reactions
Density functional theory (DFT) calculations
Pentacyclic structure
Retigerane-type sesterterpenoids
Ring cyclization
Steric inversion
Terpene cyclases
Terpenoid biosynthesis.

ACS
JACS Au

Journal: JACS Au
Publisher: ACS
Article Title: DFT Study on Retigerane-Type Sesterterpenoid Biosynthesis: Initial Conformation of GFPP Regulates Biosynthetic Pathway, Ring-Construction Order and Stereochemistry
Authors: Yuichiro Watanabe, Takahiro Hashishin, Hajime Sato, Taro Matsuyama, Masaya Nakajima, Jun-ichi Haruta and Masanobu Uchiyama
Paper link: https://pubs.acs.org/doi/10.1021/jacsau.4c00313
Journal issue link: https://pubs.acs.org/toc/jaaucr/4/9